Professor Eva Hevia

Pure and Applied Chemistry

Publications

Alkali metal effects in trans-metal-trapping (TMT) : comparing LiTMP with NaTMP in cooperative MTMP/Ga(CH2SiMe3)3 metalation reactions
McLellan Ross, Uzelac Marina, Bole Leonie J, Gil-Negrete Jose Maria, Armstrong David R, Kennedy Alan R, Mulvey Robert E, Hevia Eva
Synthesis (2018)
Structural and synthetic insights into pyridine homocouplings mediated by a β-diketiminato magnesium amide complex
Hevia Eva, McLellan Ross, Davin Laia, Clegg William, Kennedy Alan, Probert Michael R
Chemistry - A European Journal (2018)
https://doi.org/10.1002/chem.201803297
Donor-influenced structure-activity correlations in stoichiometric and catalytic reactions of lithium monoamido-monohydrido-dialkylaluminates
Lemmerz Lara E, McLellan Ross, Judge Neil R, Kennedy Alan R, Orr Samantha A, Uzelac Marina, Hevia Eva, Robertson Stuart D, Okuda Jun, Mulvey Robert E
Chemistry - A European Journal Vol 24, pp. 9940-9948 (2018)
https://doi.org/10.1002/chem.201801541
The future of polar organometallic chemistry written in bio-based solvents and water
García-Álvarez Joaquín, Hevia Eva, Capriati Vito
Chemistry - A European Journal (2018)
https://doi.org/10.1002/chem.201802873
Exploiting synergistic effects in organozinc chemistry for direct stereoselective C‐glycosylation reactions at room temperature
Hernan-Gomez Alberto, Orr Samantha, Uzelac Marina, Kennedy Alan, Barroso Santiago, Jusseau Xavier, Lemaire Sebastien, Hevia Eva
Angewandte Chemie International Edition (2018)
https://doi.org/10.1002/anie.201805758
Molecular manipulations of a utility nitrogen-heterocyclic carbene by sodium magnesiate complexes and transmetallation chemistry with gold complexes
Hevia Eva, Hernán-Gómez Alberto, Uzelac Marina, Baillie Sharon, Armstrong David, Kennedy Alan, Fuentes Maria Ángeles
Chemistry - A European Journal (2018)
https://doi.org/10.1002/chem.201802008

more publications

Professional activities

Universidad de Oviedo (Spain), External PhD Examiner
External Examiner
21/3/2016
Durham University, Departmental Colloquium
Contributor
11/2015
Keynote speaker at New perspectives in asymmetric and organometallic synthesis Symposium, 6th edition
Keynote/plenary speaker
10/2015
Plenary speaker at Annual Meeting of the RSC Main Group Chemistry Interest Group, London, UK
Keynote/plenary speaker
11/9/2015
Keynote speaker at the XXXV Biannual Congress of the Spanish Royal Society of Chemistry, La Coruña, Spain, July 2015.
Keynote/plenary speaker
7/2015
Keynote speaker at 14th International Syposium on Inorganic Ring Systems (IRIS 14), Regensburg, Germany, July 2015.
Keynote/plenary speaker
7/2015

more professional activities

Projects

Enabling industrial deployment of deep eutectic solvents through manufacturing tools
Hevia, Eva (Principal Investigator)
01-Jan-2019 - 28-Jan-2022
Doctoral Training Partnership (DTP 2016-2017 University of Strathclyde) | Gauld, Richard Mackay
Mulvey, Robert (Principal Investigator) Hevia, Eva (Co-investigator) Gauld, Richard Mackay (Research Co-investigator)
01-Jan-2016 - 01-Jan-2020
Towards a Paradigm Shift in the Principles and Practice of Polar Organometallic Chemistry
Hevia, Eva (Principal Investigator) Mulvey, Robert (Co-investigator)
"Polar organometallic chemistry provides an essential toolkit for transforming inert bonds into reactive bonds to make new compounds and materials. Very few aromatic molecules (e.g., pharmaceuticals, agrochemicals, perfumes) are made without polar organometallic chemistry being practiced at some stage in their manufacture. Though this chemistry has a long and successful history, it is currently at an exciting crossroads in its development with seemingly impossible challenges within it now on the verge of becoming possible. This project is designed towards fundamentally reforming the practice of polar organometallic chemistry making it more air and moisture compatible, greener, more atom-economical and sustainable. Research will focus on the synthesis, cultivation and exploitation of new s-block metal multicomponent reagents made by co-complexation protocols. Preliminary work has shown that mixing different components within the same environment (for example, two distinct metal complexes; or one metal but with an assortment of ligands) can lead to useful synergistic effects not possible with unmixed systems. The scope of the chemistry and the ability to construct new compounds and new materials to meet societal needs are thus greatly broadened.

Based on earth-abundant metals, these co-complex reagents will be screened in key organic transformations, focusing on deprotonative metallation and metal-halogen exchange reactions as well as in tandem C-C bond forming methods (as an alternative to more expensive and less environmentally benign transition-metal-mediated approaches) targeting synthetically relevant organic substrates. Stoichiometric reactions will be upgraded to catalytic regimes to establish the ground rules for s-block synergistic catalysis focusing on intramolecular hydroamination reactions of a range of unsaturated molecules.

A key objective of the project is to pioneer and extend the use of multicomponent polar organometallic reagents in Deep Eutectic Solvents (DESs). These DESs will provide more cost-effective, greener and biorenewable reaction media to those volatile organic solvents (VOC's) in which most polar organometallic chemistry is carried out today. Progress in this aim will go a long way to eventually realising the impossible challenge in polar organometallic chemistry of synthesising and utilising chemoselective organometallic reagents under air and/or in aqueous media. Dispensing with the need for a dry inert atmosphere would have genuine worldwide implications for the practice of polar organometallic chemistry both in academia and industry."
08-Jan-2015 - 07-Jan-2019
Doctoral Training Partnership (DTP - University of Strathclyde) | Pollard, Victoria
Mulvey, Robert (Principal Investigator) Hevia, Eva (Co-investigator) Pollard, Victoria (Research Co-investigator)
01-Jan-2015 - 01-Jan-2019
Doctoral Training Partnership (DTP - University of Strathclyde) | Fairley, Michael
Hevia, Eva (Principal Investigator) O'Hara, Charles (Co-investigator) Fairley, Michael (Research Co-investigator)
01-Jan-2015 - 01-Jan-2019
Epsrc Doctoral Training Grant | Maddock, Lewis Caradoc Huw
Hevia, Eva (Principal Investigator) Mulvey, Robert (Co-investigator) Maddock, Lewis Caradoc Huw (Research Co-investigator)
01-Jan-2012 - 27-Jan-2016

more projects

Address

Pure and Applied Chemistry
Royal College Building

Location Map

View University of Strathclyde in a larger map