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Professor Robert Mulvey

Pure and Applied Chemistry

Personal statement

Currently the Mulvey group is developing the special synergistic chemistry that can be created through combining distinct components (mixtures of different metals and different ligands) within the same molecular environment.  Fundamentally it could be said that mixing two distinct metal compounds, for example a lithium amide and a magnesium bisalkyl, produces a heterometallic molecule which acts neither as a lithium nor a magnesium compound but a compound of a unique new metallic element!  Novel chemistry, beyond the scope of conventional homometallic reagents, is the reward. This idea has been applied to metallation chemistry.  Metallation (transforming inert C-H bonds to reactive, useful C-Metal bonds) is one of the most important bond-making tools in chemistry, used routinely in synthetic laboratories worldwide, and increasingly employed from milligram to ton scales in fine chemical and pharmaceutical manufacture.  In alkali-metal-mediated metallation the alkali metal is the catalyst while the formally less reactive metal (for example, magnesium or zinc) executes the deprotonation (low polarity metallation).  Major challenges are to turn stoichiometric metallation reactions into catalytic processes and to invent ways of achieving unusual regioselectivities across a broad range of substrates.

For full free access to the latest paper on his synergistic mixed-metal research done in collaboration with Dr O’Hara and published in the journal Science (on14 November 2014, Issue 6211, Vol. 346, Pages 834-837) please use the links below.

Abstract: http://www.sciencemag.org/cgi/content/abstract/346/6211/834?ijkey=kaWzHVOzgowEk&keytype=ref&siteid=sci

Reprint: http://www.sciencemag.org/cgi/rapidpdf/346/6211/834?ijkey=kaWzHVOzgowEk&keytype=ref&siteid=sci

Full Text: http://www.sciencemag.org/cgi/content/full/346/6211/834?ijkey=kaWzHVOzgowEk&keytype=ref&siteid=sci

 

Biography

Robert Emmet Mulvey was born in Glasgow, Scotland in 1959.  He received his first degree (BSc. in Chemistry with 1st class Honours) and his Ph.D. (in organolithium chemistry under the direction of Dr Ron Snaith) at the University of Strathclyde in 1981 and 1984 respectively.  Following two years as a postdoctoral fellow at the University of Durham (in the group of Professor Ken Wade), he returned to Strathclyde in 1986 and was promoted to a Professorship in 1995.  To date he has published over 250 research papers and several book chapters.  Exceeding £3M in total as PI, his career research income includes over £2.1M from EPSRC.  A Fellow of the Royal Society of Edinburgh (FRSE), his research on polar organometallic chemistry has won him several awards and prizes as detailed below.  Most recently his work was honoured by the GDCh Arfvedson Schlenk Prize for 2013, awarded for “outstanding achievements in discovering synergistic effects of mixed main group metal compositions”.  Previously on the international advisory board of the ACS journal Organometallics, he joined the editorial board of Chemistry – A European Journal in 2014.

Publications

Contrasting synergistic heterobimetallic (Na-Mg) and homometallic (Na or Mg) bases in metalation reactions of dialkylphenylphosphines and dialkylanilines : lateral vs ring selectivities
Stevens MIchael A, Hashim Fairuz H., Gwee Eunice S. H., Izgorodina Ekaterina I., Mulvey Robert E., Blair Victoria L.
Chemistry - A European Journal, (2018)
Donor-influenced structure-activity correlations in stoichiometric and catalytic reactions of lithium monoamido-monohydrido-dialkylaluminates
Lemmerz Lara E., McLellan Ross, Judge Neil R., Kennedy Alan R., Orr Samantha A., Uzelac Marina, Hevia Eva, Robertson Stuart D., Okuda Jun, Mulvey Robert E.
Chemistry - A European Journal Vol 24, pp. 9940-9948, (2018)
http://dx.doi.org/10.1002/chem.201801541
Comparing neutral (monometallic) and anionic (bimetallic) aluminium complexes in hydroboration catalysis : influences of lithium cooperation and ligand set
Pollard Victoria A., Fuentes M. Àngeles, Kennedy Alan R., McLellan Ross, Mulvey Robert E.
Angewandte Chemie, (2018)
http://dx.doi.org/10.1002/anie.201806168
Trans-metal-trapping : concealed crossover complexes en route to transmetallation?
Uzelac Marina, Mulvey Robert E.
Chemistry - A European Journal Vol 24, pp. 7786-7793, (2018)
http://dx.doi.org/10.1002/chem.201800489
Lithium diamidodihydridoaluminates : bimetallic cooperativity in catalytic hydroboration and metallation applications
Pollard Victoria A., Orr Samantha A., McLellan Ross, Kennedy Alan R., Hevia Eva, Mulvey Robert E.
Chemical Communications Vol 54, pp. 1233-1236, (2018)
http://dx.doi.org/10.1039/C7CC08214B
1-Alkali-metal-2-alkyl-1,2-dihydropyridines : soluble hydride surrogates for catalytic dehydrogenative coupling and hydroboration applications
McLellan Ross, Kennedy Alan R., Mulvey Robert E., Orr Samantha A., Robertson Stuart D.
Chemistry - A European Journal Vol 23, pp. 16853-16861, (2017)
http://dx.doi.org/10.1002/chem.201703609

more publications

Research interests

Career History

2011   Appointed to the 1919 Chair of Inorganic Chemistry, University of Strathclyde.

1995   Professor and Head of Inorganic Chemistry, University of Strathclyde.

1993   Senior Lecturer in Chemistry, University of Strathclyde.

1991   Lecturer in Chemistry, University of Strathclyde.

1986   Royal Society 1983 University Research Fellow, University of          Strathclyde.

1984   Senior Research Assistant in Chemistry, University of Durham.

 

Awards and Fellowships

2013     Gesellschaft Deutscher Chemiker Arfvedson Schlenk Prize (2013): Awarded for “outstanding achievements in discovering synergistic effects of mixed main group metal compositions”.

2009-2014 Royal Society Wolfson Research Merit Award: Awarded for the study of “synergic mixed-metal chemistry: metallation and inverse crown applications”.

2004   Royal Society Leverhulme Trust Senior Research Fellowship: Awarded by the Royal Society for the study of “molecular synergy and inverse crown ring chemistry”.

2002   RSC Main Group Element Award: Given by the Royal Society of Chemistry for “elegant contributions to the metallo-organic and cluster chemistry of the alkali and alkaline earth metals”.

2001   Fellow of the Royal Society of Edinburgh: Elected to the Fellowship of the Royal Society of Edinburgh (FRSE).

1988   RSC Meldola Medal: Given by the Society of Maccabaeans and the Royal Society of Chemistry in respect of work on the synthesis and characterisation of the unprecedented species of lithium oligomer chemistry.

1986   Royal Society 1983 University Research Fellowship: Host institution, University of Strathclyde.  Title of research project “Explorative coordination chemistries of Cu(I)/Zn(II) versus the alkaline/alkaline-earth metals”.

1984   The Ritchie Prize (1984): Given on the recommendation of the Chairman of the Department of Pure and Applied Chemistry, University of Strathclyde, to the PhD candidate “who presents the thesis which best combines excellence of scientific work with quality of presentation”.

Professional activities

28th International Conference in Organometallic Chemistry
Chair
19/7/2018
Alkali Metal Mediation in Synergistic Synthesis and Homogeneous Catalysis
Speaker
18/6/2018
Alkali Metal Mediation: Synergistic Synthesis and Trans-Metal-Trapping
Speaker
5/6/2018
Alkali Metal Mediation in Synergistic Synthesis and Homogeneous Catalysis
Speaker
4/6/2018
Alkali Metal Mediation in Synergistic Synthesis and Homogeneous Catalysis
Speaker
14/5/2018
University of Regensburg
Visiting researcher
1/5/2018

more professional activities

Projects

Doctoral Training Partnership (DTP 2016-2017 University of Strathclyde) | Gauld, Richard Mackay
Mulvey, Robert (Principal Investigator) Hevia, Eva (Co-investigator) Gauld, Richard Mackay (Research Co-investigator)
Period 01-Oct-2016 - 01-Apr-2020
Doctoral Training Partnership (DTP - University of Strathclyde) | Pollard, Victoria
Mulvey, Robert (Principal Investigator) Hevia, Eva (Co-investigator) Pollard, Victoria (Research Co-investigator)
Period 01-Oct-2015 - 01-Apr-2019
Sodium Carboxylates in Diesel Fuels
Mulvey, Robert (Principal Investigator)
Period 01-Oct-2016 - 31-Mar-2020
Doctoral Training Grant 2006 | Herd, Emma
Hevia, Eva (Principal Investigator) Mulvey, Robert (Co-investigator)
Period 01-Jul-2007 - 15-Nov-2014
EPSRC Doctoral Training Grant - DTA, University of Strathclyde | Orr, Samantha Alana
Mulvey, Robert (Principal Investigator) O'Hara, Charles (Co-investigator)
Period 01-Oct-2013 - 20-Sep-2017
Epsrc Doctoral Training Grant | Maddock, Lewis Caradoc Huw
Hevia, Eva (Principal Investigator) Mulvey, Robert (Co-investigator)
Period 01-Oct-2012 - 27-Oct-2016

more projects

Address

Pure and Applied Chemistry
Royal College Building

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